Conference 11772 > Paper 11772-55
Paper 11772-55

Temperature effect on spectral properties of cesium lead bromide perovskite nanocrystals in borogermanate glass

Abstract

This work is devoted to the study of phase transitions in CsPbBr3 perovskite nanocrystals nucleated in borogermanate glass. Perovskite nanocrystals are obtained by bulk crystallization in a glass matrix. A series of glass samples with nanocrystals of different sizes is investigated. Upon heating, the temperature dependence of the 1S exciton intensity for the entire series of samples shows the presence of three phase transitions: in the range 130-150, 440-450, and 510-515°C. The first phase transition refers to the transition from a tetragonal to a cubic structure. The last phase transition is associated with the melting of the crystalline phase. The phase transition at 440°С is declared for the first time. Upon cooling, the temperature curve shows the presence of only one phase transition in the region of 330°C, which is associated with the crystallization onset of CsPbBr3 perovskite nanocrystals in glass matrix.

Presenter

ITMO Univ. (Russian Federation)
Presenter/Author
ITMO Univ. (Russian Federation)
Author
Aleksandra Pavliuk
ITMO Univ. (Russian Federation)
Author
ITMO Univ. (Russian Federation)
Author
ITMO Univ. (Russian Federation)
Author
ITMO Univ. (Russian Federation)
Author
Kseniia Oreshkina
ITMO Univ. (Russian Federation)
Author
Victor Dubrovin
ITMO Univ. (Russian Federation)
Author
ITMO Univ. (Russian Federation)
Author
Alexandre Ignatiev
ITMO Univ. (Russian Federation)
Author
ITMO Univ. (Russian Federation)
Author
Peter the Great St. Petersburg Polytechnic Univ. (Russian Federation)