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Proceedings Paper

Chemical Modification Of Oxidized And Silicon Oxide Covered Aluminium Surfaces Studied By FTIR-MSR Spectroscopy
Author(s): A. H.M. Sondag; M. C. Raas; F. J. Touwslager; J. J. Ponjee
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Paper Abstract

Multiple Specular Reflectance (MSR) infrared reflection-absorption spectroscopy has been applied to study surface modification by organosilane (sub)monomolecular layers. The spectrum of octadecyldimethylmethoxysilane immobilized on an oxidized aluminium substrate is compared to the absorption spectra of the monomer and the disiloxane condensation product. Formation of hydroxyl groups on a Si02 covered aluminium substrate by a UV-ozon treatment is shown. Simultaneously, organic contaminants are removed from the surface by the UV-ozon treatment. The chemisorption of 3-methacryloxypropyldimethylethoxysilane on UV-ozon treated Si02 has been examined at different surface coverages. An increase of the number of organosilane species at the surface is accompanied by a decrease of surface hydroxyl groups.

Paper Details

Date Published: 1 December 1989
PDF: 2 pages
Proc. SPIE 1145, 7th Intl Conf on Fourier Transform Spectroscopy, (1 December 1989); doi: 10.1117/12.969484
Show Author Affiliations
A. H.M. Sondag, Philips Research Laboratories (The Netherlands)
M. C. Raas, Philips Research Laboratories (The Netherlands)
F. J. Touwslager, Philips Research Laboratories (The Netherlands)
J. J. Ponjee, Philips Research Laboratories (The Netherlands)

Published in SPIE Proceedings Vol. 1145:
7th Intl Conf on Fourier Transform Spectroscopy
David G. Cameron, Editor(s)

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