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Proceedings Paper

Spectroscopy And Reaction Kinetics Of Photolytically Generated Fe(CO)[sub]x[/sub] (X = 2,3,4)
Author(s): A J Ouderkirk; T A Seder; Eric Weitz
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Paper Abstract

An apparatus for the gas phase infrared spectroscopic detection of coordinatively un-saturated metal carbonyls is described. Coordinatively unsaturated species are produced by UV photolysis. Infrared spectra of coordinatively unsaturated iron carbonyls are reported for the carbonyl stretch region. Rate constants for the reaction of Fe(C0)3 and Fe(C0)4 with CO are also reported. The photophysics of Fe(C0)x formation is discussed.

Paper Details

Date Published: 31 May 1984
PDF: 6 pages
Proc. SPIE 0458, Applications of Lasers to Industrial Chemistry, (31 May 1984); doi: 10.1117/12.939425
Show Author Affiliations
A J Ouderkirk, Northwestern University (United States)
T A Seder, Northwestern University (United States)
Eric Weitz, Northwestern University (United States)

Published in SPIE Proceedings Vol. 0458:
Applications of Lasers to Industrial Chemistry
Richard L. Woodin; Andrew Kaldor, Editor(s)

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