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Proceedings Paper

High Resolution Spectra Of Some Silicon Compounds
Author(s): S. E. Rodgers; V. F. Kalasinsky
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Paper Abstract

The infrared spectra of gaseous vinylsilane, cyclopropylsilane, vinyltrichlorosilane, cyclopropyltrichlorosilane, and silacyclopentane have been recorded. Barriers to internal rotation have been calculated for vinylsilane and cyclopropylsilane from an analysis of combination and difference bands associated with the Si-H stretches. Vibrational assignments have been made for vinyltrichlorosilane and cyclopropylsilane. High resolution spectra of the combination and difference bands involving the Si-H stretches and the ring-puckering vibration in silacyclopentane have been analyzed, and the new assignment is found to be completely consistent with existing low-frequency data. The structural implications of the results are discussed.

Paper Details

Date Published: 29 October 1981
PDF: 2 pages
Proc. SPIE 0289, 1981 Intl Conf on Fourier Transform Infrared Spectroscopy, (29 October 1981); doi: 10.1117/12.932194
Show Author Affiliations
S. E. Rodgers, Mississippi State University (United States)
V. F. Kalasinsky, Mississippi State University (United States)

Published in SPIE Proceedings Vol. 0289:
1981 Intl Conf on Fourier Transform Infrared Spectroscopy
Hajime Sakai, Editor(s)

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