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Proceedings Paper

Fourier Transform Far Infrared Studies Of Matrix-Isolated Alcohols
Author(s): Werner A.P. Luck; Otto Schrems
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Paper Abstract

Low temperature matrix spectra of alcohols have been investigated in the region 50 cm-1; to 400 cm-1. Vibration frequencies associated with the hydrogen-bonded system R-OH...0 and the torsional modes have been assigned. From studies of the pure alcohols and from the concentration dependency of the observed bands it was found that the hydrogen bond stretching frequencies (νσ) appear in the 100 - 160 cm-1; range. At higher M/A ratios the OH torsion modes (τOH) were identified in the 200 - 300 cm-1; region. The influence of various matrix gases on the absorption frequencies has also been studied.

Paper Details

Date Published: 29 October 1981
PDF: 3 pages
Proc. SPIE 0289, 1981 Intl Conf on Fourier Transform Infrared Spectroscopy, (29 October 1981);
Show Author Affiliations
Werner A.P. Luck, University of Marburg (Germany)
Otto Schrems, University of Marburg (Germany)

Published in SPIE Proceedings Vol. 0289:
1981 Intl Conf on Fourier Transform Infrared Spectroscopy
Hajime Sakai, Editor(s)

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