
Proceedings Paper
Understanding and mitigating effects of nonuniformities on reliability of thin film photovoltaicsFormat | Member Price | Non-Member Price |
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Paper Abstract
Thin-film photovoltaics (PV) are sensitive to lateral nonuniformities (LN) that manifest themselves in spatial
variations of the device local characteristics and in the variability of the measured parameters between nominally
identical devices. LN affect all the aspects of device operations and stability and appear as a hidden cost of the
otherwise inexpensive technology. They are omnipresent as originating from multiple factors typical of thin-film
PV: deposition geometry, wet and heat treatments, dispersion in grain and amorphous phase parameters, and
fluctuations in metal-semiconductor barriers. LN are seen in the device mappings, including that of PL, Voc,
OBIC, EBIC, thermography, and electroluminescence. Stresses localized on certain vulnerable spots drive the
entire device degradation. We present a general summary of physical processes related to LN, including modeling
aspects, characteristic length and variability scales, statistics, degradation mechanisms, and superadditive effects
between different device components, such as a negative correlation between the resistive and LN related loss,
and a positive correlation between LN and device shunting failures under stress. We then review the known
practical techniques of mitigating LN effects patented by different groups from 1970s to nowadays and show how
nonuniformity treatments play the key role in the existing technologies.
Paper Details
Date Published: 20 August 2009
PDF: 15 pages
Proc. SPIE 7412, Reliability of Photovoltaic Cells, Modules, Components, and Systems II, 74120L (20 August 2009); doi: 10.1117/12.828937
Published in SPIE Proceedings Vol. 7412:
Reliability of Photovoltaic Cells, Modules, Components, and Systems II
Neelkanth G. Dhere; John H. Wohlgemuth; Dan T. Ton, Editor(s)
PDF: 15 pages
Proc. SPIE 7412, Reliability of Photovoltaic Cells, Modules, Components, and Systems II, 74120L (20 August 2009); doi: 10.1117/12.828937
Show Author Affiliations
Victor G. Karpov, Univ. of Toledo (United States)
Diana Shvydka, Univ. of Toledo (United States)
Published in SPIE Proceedings Vol. 7412:
Reliability of Photovoltaic Cells, Modules, Components, and Systems II
Neelkanth G. Dhere; John H. Wohlgemuth; Dan T. Ton, Editor(s)
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