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Proceedings Paper

Silicon and tungsten oxide nanostructures for water splitting
Author(s): Karla R. Reyes Gil; Joshua M. Spurgeon; Nathan S. Lewis
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Paper Abstract

Inorganic semiconductors are promising materials for driving photoelectrochemical water-splitting reactions. However, there is not a single semiconductor material that can sustain the unassisted splitting of water into H2 and O2. Instead, we are developing a three part cell design where individual catalysts for water reduction and oxidation will be attached to the ends of a membrane. The job of splitting water is therefore divided into separate reduction and oxidation reactions, and each catalyst can be optimized independently for a single reaction. Silicon might be suitable to drive the water reduction. Inexpensive highly ordered Si wire arrays were grown on a single crystal wafer and transferred into a transparent, flexible polymer matrix. In this array, light would be absorbed along the longer axial dimension while the resulting electrons or holes would be collected along the much shorter radial dimension in a massively parallel array resembling carpet fibers on a microscale, hence the term "solar carpet". Tungsten oxide is a good candidate to drive the water oxidation. Self-organized porous tungsten oxide was successfully synthesized on the tungsten foil by anodization. This sponge-like structure absorbs light efficiently due to its high surface area; hence we called it "solar sponge".

Paper Details

Date Published: 20 August 2009
PDF: 11 pages
Proc. SPIE 7408, Solar Hydrogen and Nanotechnology IV, 74080S (20 August 2009); doi: 10.1117/12.825545
Show Author Affiliations
Karla R. Reyes Gil, California Institute of Technology (United States)
Joshua M. Spurgeon, California Institute of Technology (United States)
Nathan S. Lewis, California Institute of Technology (United States)

Published in SPIE Proceedings Vol. 7408:
Solar Hydrogen and Nanotechnology IV
Frank E. Osterloh, Editor(s)

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