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Proceedings Paper

Structure properties of copper-containing nanoparticles in polyethylene matrix
Author(s): M. N. Zhuravleva; K. V. Zapsis; Ju. G. Konyukhova; I. D. Kosobudsky; V. I. Kochubey; N. M. Ushakov
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Paper Abstract

Copper-containing nanoparticles synthesized in high-pressure polyethylene matrix by the method of thermal decomposition of (CH3COO)2Cu H2O are presented. Average dimensions of nanoparticles and size distribution were determined by transmission electron microscopy and X-ray phase analysis. It was shown that, with increasing copper concentration, the nanoparticles increase in size from 6 to 18 nm. The structure of copper-containing nanoparticles was determined by the method of EXAFS spectroscopy in fluorescence mode and in transmission one. It was shown that the samples containing 3 wt% and 5 wt% of copper are most likely to include CuO particles with tenorite structure. When the copper concentration is increased to 10 wt%, the nanoparticles contain Cu2O and metallic copper phases. An increase in copper concentration to 40 wt% results in complication of the composition and the structure of the particles.

Paper Details

Date Published: 5 March 2008
PDF: 8 pages
Proc. SPIE 7009, Second International Conference on Advanced Optoelectronics and Lasers, 700916 (5 March 2008); doi: 10.1117/12.793851
Show Author Affiliations
M. N. Zhuravleva, Saratov State Technical Univ. (Russia)
K. V. Zapsis, Institute of Radio Engineering and Electronics (Russia)
Ju. G. Konyukhova, Saratov State Univ. (Russia)
I. D. Kosobudsky, Saratov State Technical Univ. (Russia)
V. I. Kochubey, Saratov State Univ. (Russia)
N. M. Ushakov, Institute of Radio Engineering and Electronics (Russia)

Published in SPIE Proceedings Vol. 7009:
Second International Conference on Advanced Optoelectronics and Lasers
Igor A. Sukhoivanov; Vasily A. Svich; Yuriy S. Shmaliy, Editor(s)

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