Share Email Print

Proceedings Paper

Partially deuterated water dimer: are there perspectives for its spectroscopic detection in the atmosphere?
Author(s): Andrei A. Vigasin; Galina V. Chlenova
Format Member Price Non-Member Price
PDF $17.00 $21.00

Paper Abstract

Recent observations of the water dimer third stretching overtone in the open atmosphere lead onto the idea to look for the signatures of partially deuterated dimers in the range of their stretching fundamentals. On the one hand, the third overtone intensity is roughly three orders of magnitude less than that in the fundamental. On the other hand, the natural abundances of the water isotopomers are known to extend below 0.2% with respect to that of the principal one. The gain can be achieved, however, because of the use of the spectral range which is less crowded by the principal water isotopologue rovibrational lines, because of significant isotopic shift of the band origin. This work is targeted at preliminary search of the suitable spectral window and other conditions which might favor the observation of partially deuterated water dimers using FTIR or tunable lasers instruments.

Paper Details

Date Published: 13 December 2006
PDF: 7 pages
Proc. SPIE 6580, 15th Symposium on High-Resolution Molecular Spectroscopy, 65800Y (13 December 2006); doi: 10.1117/12.724962
Show Author Affiliations
Andrei A. Vigasin, General Physics Institute (Russia)
Galina V. Chlenova, Obukhov Institute of Atmospheric Physics (Russia)

Published in SPIE Proceedings Vol. 6580:
15th Symposium on High-Resolution Molecular Spectroscopy
Yurii N. Ponomarev; Semen N. Mikhailenko; Leonid N. Sinitsa, Editor(s)

© SPIE. Terms of Use
Back to Top
Sign in to read the full article
Create a free SPIE account to get access to
premium articles and original research
Forgot your username?