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Proceedings Paper

Determination of potential energy curves by regularized inverted perturbation approach: application to alkali dimers
Author(s): Anna Grochola; Wlodzimierz Jastrzebski; Pawel Kowalczyk; Asen Pashov
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Paper Abstract

We describe a modification of the inverted perturbation approach method allowing to construct physically sensible potential energy curves for electronic states of diatomic molecules even when some parts of the potential are not adequately characterized by the experimental data. The method is based on a simple regularization procedure, imposing an additional constraint on the constructed potential curve. In the present work it is applied to the double minimum 41Σ+u state of Na2, observed experimentally by polarization labeling spectroscopy technique.

Paper Details

Date Published: 22 April 2005
PDF: 5 pages
Proc. SPIE 5830, 13th International School on Quantum Electronics: Laser Physics and Applications, (22 April 2005); doi: 10.1117/12.618752
Show Author Affiliations
Anna Grochola, Warsaw Univ. (Poland)
Wlodzimierz Jastrzebski, Institute of Physics (Poland)
Pawel Kowalczyk, Warsaw Univ. (Poland)
Asen Pashov, Institute for Scientific Research in Telecommunications (Bulgaria)

Published in SPIE Proceedings Vol. 5830:
13th International School on Quantum Electronics: Laser Physics and Applications
Peter A. Atanasov; Sanka V. Gateva; Lachezar A. Avramov; Alexander A. Serafetinides, Editor(s)

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