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Proceedings Paper

FTIR studies of the reaction between atomic oxygen and CH3Br, CH2Br2, and CHBr3 in argon matrices
Author(s): Emilie Lasson; Peter Klaeboe; Claus J. Nielsen
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Paper Abstract

The reaction of singlet atomic oxygen with CH3Br, CH2Br2, CHBr3 and CDBr3 trapped in argon matrices at 15 K have been studied by FTIR and by UV spectroscopy. CHBr3 and O(1D) reacts in the matrix to form COBr2 and HBr or HCOBr and Br2. The reaction between O(1D) and CH2Br2 in the matrix appears to lead directly to a HBr(DOT)(DOT)HBr(DOT)(DOT)CO complex while in the reaction between CH3Br and O(1D) the major product seems to be a quite photostable complex between H2CO and HBr.

Paper Details

Date Published: 1 March 1992
PDF: 2 pages
Proc. SPIE 1575, 8th Intl Conf on Fourier Transform Spectroscopy, (1 March 1992); doi: 10.1117/12.56489
Show Author Affiliations
Emilie Lasson, Univ. of Oslo (Norway)
Peter Klaeboe, Univ. of Oslo (Norway)
Claus J. Nielsen, Univ. of Oslo (Norway)

Published in SPIE Proceedings Vol. 1575:
8th Intl Conf on Fourier Transform Spectroscopy
Herbert Michael Heise; Ernst Heiner Korte; Heinz W. Siesler, Editor(s)

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