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Proceedings Paper

Fiber optic sensors for an in-situ monitoring of moisture and pH value in reinforced concrete
Author(s): Walter Grahn; Pavel Makedonski; Juergen Wichern; Wolfgang Kowalsky; Stefan Wiese
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Paper Abstract

Concrete structures such as social buildings and bridges are important economic goods. Thus, maintenance and preservation of these structures are of major interest. Buildings of reinforced concrete are exposed to a variety of damaging influences. In particular, moisture has an important influence on the lifetime of concrete structures. This is caused by the involvement of free water in corrosion of the steel, and the fact that water acts as transport medium for damaging ions such as chloride, sulfate, carbonate and ammonium. Thus, we designed and developed an integrated fiberoptical sensor system, which allows in-situ non- destructive long-term monitoring of concrete structures. As moisture indicator we use a pyridinium-N-phenolat betainital dye, which shows a strong solvatochromic behavior in the ultraviolet-visible spectral range (UV-VIS). The dye is embedded in a polymer matrix, whose moderate polarity is enhanced by free water diffusing into the sensor. This leads to a continuous hypsochromic shift of the absorption spectrum according to the water concetration. Another appropriate dye is 4-amino-N-methylphthalimid, which shows a similar behavior in its fluorescent spectra, and presently we are developing its derivatives and suitable polymer matrices. The determination of the pH-value of concrete is of major importance for the assessment of acidic attacks which may lead to serious damage in reinforced concrete, as the embedded steel structures exhibit long-term stability (i.e. resistance to corrosion) only at pH-values of 9 or higher. Therefore we have developed a fiberoptical sensor system for the measurement of pH-values in concrete consisting of pH- indicator dyes immobilized in a highly immobilized in a highly hydrophilic polymer matrix. Any change in pH-value of the wet concrete material is indicated by a color change of the dye/polymer system. The sensor system displays long term stability even in aggressive media of pH12 - 13.

Paper Details

Date Published: 17 January 2002
PDF: 10 pages
Proc. SPIE 4480, Imaging Spectrometry VII, (17 January 2002); doi: 10.1117/12.453362
Show Author Affiliations
Walter Grahn, Technische Univ. Braunschweig (Germany)
Pavel Makedonski, Technische Univ. Braunschweig (Germany)
Juergen Wichern, Technische Univ. Braunschweig (Germany)
Wolfgang Kowalsky, Technische Univ. Braunschweig (Germany)
Stefan Wiese, Technische Univ. Braunschweig (Germany)

Published in SPIE Proceedings Vol. 4480:
Imaging Spectrometry VII
Michael R. Descour; Sylvia S. Shen, Editor(s)

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