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Proceedings Paper

Synthesis and characterization of optically nonlinear and light-emitting lanthanide borates
Author(s): Henry Giesber; John M. Ballato; William T. Pennington Jr.; Joseph W. Kolis
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Paper Abstract

Lanthanide borates, LnBO3, were prepared via hydrothermal methods, specifically supercritical basic water, in sizes up to 3 X 0.5 X 0.5 mm and their crystallographic, physical, and optical properties studied. The materials are thermally stable up to 1000 degrees C and their crystal structure, although previously thought to be centric orthorhombic, is shown to be orthorhombic yet acentric as is confirmed by the observance of second harmonic generated light. Absorption and luminescence from the NdBO3 and PrBO3 is provided and discussed, along with the corroboration that these materials have bandgaps well above 5 eV. This work marks these lanthanide borates as candidate materials for deep-UV and nonlinear optical applications.

Paper Details

Date Published: 2 November 2001
PDF: 6 pages
Proc. SPIE 4452, Inorganic Optical Materials III, (2 November 2001); doi: 10.1117/12.446881
Show Author Affiliations
Henry Giesber, Clemson Univ. (United States)
John M. Ballato, Clemson Univ. (United States)
William T. Pennington Jr., Clemson Univ. (United States)
Joseph W. Kolis, Clemson Univ. (United States)

Published in SPIE Proceedings Vol. 4452:
Inorganic Optical Materials III
Alexander J. Marker III; Mark J. Davis, Editor(s)

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