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Proceedings Paper

IR spectroscopy of interhalides XF3 and XF5 (X = Cl, Br)
Author(s): Shavkat Sh. Nabiev
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Paper Abstract

Interhalogens XF3 and XF5 (X equals Cl,Br) are widely used for reprocessing of nuclear materials, in electronic and iron-and-steel industries. At the same time XF3 and XF5 may be regarded among most dangerous components in the plumes of emergency ejections of these manufactures. The Cl and Br fluorides interact actively with atmospheric gases resulting in the formation of hydrogen halogen, Cl and Br oxyfluorides and oxides which are transformed into stable complexes (HHal)x...(H2O)y, where Hal equals F, Cl, Br; x + y >= 2. A study into reaction mechanisms with a participation of the XF3 and XF5 compounds, their secondary compounds and the applicability of the remote laser control techniques requires comprehensive information on vibration spectra of interhalogens.

Paper Details

Date Published: 25 January 2000
PDF: 6 pages
Proc. SPIE 4063, 13th Symposium and School on High-Resolution Molecular Spectroscopy, (25 January 2000); doi: 10.1117/12.375372
Show Author Affiliations
Shavkat Sh. Nabiev, Kurchatov Institute (Russia)

Published in SPIE Proceedings Vol. 4063:
13th Symposium and School on High-Resolution Molecular Spectroscopy
Leonid N. Sinitsa, Editor(s)

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