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Proceedings Paper

Novel laser breakdown spectrometer for environmental monitoring
Author(s): Sergey B. Mirov; Robert E. Pitt; Alex Yu. Dergachev; Wonwoo Lee; Dmitri V. Martyshkin; Olga D. Mirov; Jeremy J. Randolph; Lawrence J. DeLucas; Christie G. Brouillette; Tasoltan T. Basiev; Yurii V. Orlovskii; Olimkhon K. Alimov; Ivan N. Vorob'ev
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Paper Abstract

A novel experimental set-up using laser-induced breakdown spectroscopy (LIBS) for environmental analyses of heavy metals is described in this paper. It is based on state-of-the-art spectroscopic equipment, advanced detectors, and laser atomizers: a 0.75 m spectrometer ARC-750, intensified TE- cooled 256 X 1024 CCD camera, probe with fiber optic guide for signal transportation, and Nd:YAG laser plasma atomizers with two different methods for sample delivery. In the first method the liquid solution containing the atoms to be investigated is drawn into the chamber of the nebulizer. The mixture passes through the nozzle, accompanied by argon gas along with formed aerosol, and enters the plasma plume, which is generated by the laser spark in argon. The second method is based on direct generating of the plasma in the water jet of a continuously circulating sample. LIBS testing of samples containing Al, Cd, Cu, Fe, Pb, Zn, and Cr ions was compared with results using atomic absorption spectrophotometry. Initial indications showed good agreement between these two methods. Detection levels of less than 100 ppb were observed for copper and chromium. The described spectroscopic system exhibits high sensitivity, accumulation of luminescence spectrum in real time; and high dynamic range for concentrations detection from 100 ppb to 1000 ppm.

Paper Details

Date Published: 30 November 1999
PDF: 8 pages
Proc. SPIE 3855, Air Monitoring and Detection of Chemical and Biological Agents II, (30 November 1999); doi: 10.1117/12.371277
Show Author Affiliations
Sergey B. Mirov, Univ. of Alabama/Birmingham (United States)
Robert E. Pitt, Univ. of Alabama/Birmingham (United States)
Alex Yu. Dergachev, Univ. of Alabama/Birmingham (United States)
Wonwoo Lee, Univ. of Alabama/Birmingham (United States)
Dmitri V. Martyshkin, Univ. of Alabama/Birmingham (United States)
Olga D. Mirov, Univ. of Alabama/Birmingham (United States)
Jeremy J. Randolph, Univ. of Alabama/Birmingham (United States)
Lawrence J. DeLucas, Univ. of Alabama/Birmingham (United States)
Christie G. Brouillette, Univ. of Alabama/Birmingham (United States)
Tasoltan T. Basiev, General Physics Institute (Russia)
Yurii V. Orlovskii, General Physics Institute (Russia)
Olimkhon K. Alimov, General Physics Institute (Russia)
Ivan N. Vorob'ev, General Physics Institute (Russia)

Published in SPIE Proceedings Vol. 3855:
Air Monitoring and Detection of Chemical and Biological Agents II
Joseph Leonelli; Mark L.G. Althouse, Editor(s)

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