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Proceedings Paper

FTIR studies of the structure of water in salt solutions
Author(s): Mladen Georgiev; N. Goutev; Zh. Nickolov; Georgy K. Georgiev; J. J. Ramsden
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Paper Abstract

The DOH system in H2O and 2 M aqueous salt solutions of NaSCN and (CH3)4NCl has been studied by the fluctuation model of hydrogen bonding. A number of quantitative parameters, characterizing the hydrogen bond network of the DOH system has been derived. The salts have an influence on the structure of the solutions in accordance with their positions in the Hofmeister series. A simple and efficient procedure for evaluation of the thermodynamical parameters of water solutions is described and verified. The specific heat values CV of the studied solutions are determined by means of the statistical integral Z(T). The values coincide very well with literature data.

Paper Details

Date Published: 7 May 1999
PDF: 5 pages
Proc. SPIE 3571, Tenth International School on Quantum Electronics: Laser Physics and Applications, (7 May 1999); doi: 10.1117/12.347625
Show Author Affiliations
Mladen Georgiev, Sofia Univ. (Bulgaria)
N. Goutev, Sofia Univ. (Bulgaria)
Zh. Nickolov, Sofia Univ. (Bulgaria)
Georgy K. Georgiev, Sofia Univ. (Bulgaria)
J. J. Ramsden, Basel Univ. (Switzerland)

Published in SPIE Proceedings Vol. 3571:
Tenth International School on Quantum Electronics: Laser Physics and Applications
Peter A. Atanasov; Dimitar V. Stoyanov, Editor(s)

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