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Proceedings Paper

In-situ STM studies of thallium underpotential deposition on Au(111) single-crystal electrode in acid solution
Author(s): Wanda Polewska; Radoslav Adzic
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Paper Abstract

The structure of electrodeposited Tl adlayers on Au(111) in 0.1 M. HClO4 has been investigated using in-situ scanning tunneling microscopy method. Incommensurate, rotated hexagonal (RHCP) Tl adlayer was found, within a wide potential window, between Tl bulk deposition at -0.7 V and -0.4 V. This adlayer is closely packed with Tl interatomic distance of 3.4 +/- 0.2 angstroms, its rotation from the gold substrate axis is 60 +/- 10 and its coverage is 0.74. At slightly more positive potentials, between -0.45 V and -0.37 V, low coverage 2 X 2 phase of Tl was found, coexisting together with RHCP monolayer. At the potential region between -0.35 V and 0.8 V both ordered Tl phases disappeared and instead the formation of considerable amount of pits at the surface has been observed.

Paper Details

Date Published: 8 April 1999
PDF: 4 pages
Proc. SPIE 3725, International Conference on Solid State Crystals '98: Epilayers and Heterostructures in Optoelectronics and Semiconductor Technology, (8 April 1999); doi: 10.1117/12.344745
Show Author Affiliations
Wanda Polewska, Poznan Univ. of Technology (Poland)
Radoslav Adzic, Brookhaven National Lab. (United States)


Published in SPIE Proceedings Vol. 3725:
International Conference on Solid State Crystals '98: Epilayers and Heterostructures in Optoelectronics and Semiconductor Technology
Antoni Rogalski; Jaroslaw Rutkowski, Editor(s)

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