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Proceedings Paper

Chemical design of inorganic nonlinear optical crystals
Author(s): B. I. Kidyarov; V. I. Kosyakov
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Paper Abstract

A brief review of the progress in the methodology of chemical design of the acentric crystals is presented primarily for nonlinear optics. The prediction and search of new crystalline phases and compounds have been carried out by the development of the matrix method in binary systems, including the salts of 1-1 and 2-1 electrolytes at first for the lead and barium salt classes. The ion radii and chemical bond lengths have been selected as the criteria in the system analysis of the interrelation between composition, structure and properties. The two areas for an initial search of new nonlinear optical materials have been proposed: the oxide salts with the short or long chemical bond length. For example two new binary nonlinear optical iodate crystals have been predicted and synthesed.

Paper Details

Date Published: 21 October 1998
PDF: 10 pages
Proc. SPIE 3485, 11th International Vavilov Conference on Nonlinear Optics, (21 October 1998); doi: 10.1117/12.328257
Show Author Affiliations
B. I. Kidyarov, Institute of Semiconductor Physics (Russia)
V. I. Kosyakov, Institute of Inorganic Chemistry (Russia)

Published in SPIE Proceedings Vol. 3485:
11th International Vavilov Conference on Nonlinear Optics
Sergei G. Rautian, Editor(s)

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