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Proceedings Paper

Fluorescence analysis of Bisphenol A photolysis under exposure to excilamps
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Paper Abstract

The influence of irradiation wavelength on the degradation of Bisphenol A (BPA) in water under the action of KrCl and XeBr excilamp radiation in a photoreactor is investigated. Fluorescent photoproducts of photodegradation of the investigated molecule is constructed. In the work fluorescent photoproducts are defined. In an excited state BPA exists in a dimeric form at a concentration above 0.1 mM. After excitation by an excilamp the main BPA photoproduct fluoresces in the region of 420 nm. This behavior is explained by the fact that the action of 222 nm radiation leads to accumulation of a stable photoproduct. This product is destroyed as well as BPA after 120 minutes of exposure. Under the action of XeBr excilamp radiation a very stable product is formed with fluorescence at 380 nm. In order to establish the mechanism of BPA photolysis the product using chromatomass spectrometryfurther research is needed.

Paper Details

Date Published: 11 December 2019
PDF: 7 pages
Proc. SPIE 11322, XIV International Conference on Pulsed Lasers and Laser Applications, 1132206 (11 December 2019); doi: 10.1117/12.2554957
Show Author Affiliations
E. N. Bocharnikova, Tomsk State Univ. (Russian Federation)
O. N. Tchaikovskaya, Tomsk State Univ. (Russian Federation)
V. S. Chaidonova, Tomsk State Univ. (Russian Federation)
J. Gomez, Univ. de Murcia (Spain)
M. Gomez, Univ. de Murcia (Spain)
M. Murcia, Univ. de Murcia (Spain)

Published in SPIE Proceedings Vol. 11322:
XIV International Conference on Pulsed Lasers and Laser Applications
Victor F. Tarasenko; Anton V. Klimkin; Maxim V. Trigub, Editor(s)

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