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Proceedings Paper

High performance roll-to-roll printed PTB7-Th/PCBM solar cells (Conference Presentation)
Author(s): Kevin L. Gu; Xiaodan Gu; Yan Zhou; Hongping Yan; Michael F. Toney; Zhenan Bao

Paper Abstract

Despite having surpassed 10% power conversion efficiency (PCE), widely held as the threshold for commercial viability, high performance organic photovoltaics (OPVs) are still mostly constrained to lab-scale devices fabricated by spin coating. Efforts to produce scalable printed OPVs trail significantly in efficiency, highlighting the need to better understand the processing-morphology-performance relationship in the context of linear printing processes. Here we investigate the OPV system PTB7-Th/PC71BM, which has demonstrated >10% PCE via spincoating but only exhibits ~1% PCE when roll-to-roll printed. Of particular interest is the ubiquitous alcohol wash post-treatment applied to the dried active layer, which induces a significant improvement in device performance, and its crucial role for printed films. While it has been speculated that the primary utility of the alcohol post-treatment is to remove the additive 1,8-diiodooctane (DIO) residue in the dried film, we find here that the wash process itself dramatically impacts morphology in printed films regardless of the presence of DIO. Here we employ various x-ray characterization techniques to probe phase separation, crystallinity, and molecular orientation, as well as in-situ grazing-incidence x-ray diffraction (in-situ GIXD) to monitor morphological evolution during the isopropanol post-treatment process. It is discovered that isopropanol induces significant donor polymer alignment and enhanced π-π degree of crystallinity. Through the understanding gained in this study, we are able to achieve a roll-to-roll printed OPV with 5% PCE, which is to our knowledge the highest reported performance for a roll-to-roll printed single junction photoactive layer on a flexible substrate.

Paper Details

Date Published: 19 September 2017
Proc. SPIE 10363, Organic, Hybrid, and Perovskite Photovoltaics XVIII, 103630G (19 September 2017); doi: 10.1117/12.2273133
Show Author Affiliations
Kevin L. Gu, Stanford Univ. (United States)
Xiaodan Gu, Stanford Univ. (United States)
Univ. of Southern Mississippi (United States)
Yan Zhou, Stanford Univ. (United States)
Hongping Yan, Stanford Univ. (United States)
SLAC National Accelerator Lab (United States)
Michael F. Toney, SLAC National Accelerator Lab. (United States)
Zhenan Bao, Stanford Univ. (United States)

Published in SPIE Proceedings Vol. 10363:
Organic, Hybrid, and Perovskite Photovoltaics XVIII
Zakya H. Kafafi; Paul A. Lane; Kwanghee Lee, Editor(s)

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