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Proceedings Paper

Novel UV probe for selective detection of Au and Pd in aqueous solutions
Author(s): A. Mironenko; M. Tutov; A. Sergeev; S. Bratskaya
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Paper Abstract

A novel turn on/off rhodamine 6G based fluorescent probe has been developed for selective detection of Au and Pd complexes in aqueous acidic solutions utilizing rhodamine spirolactam ring-opening process. Rhodamine derivatives have been widely used as versatile platforms for fluorescent probes. The newly designed probe reacts with [AuCl4]- and [PdCl4]2- to generate a product that has distinctly different optical properties. The probe undergoes a remarkable change in its absorption and emission spectrum upon addition of Au and Pd complexes that is associated with a discoloration and quenching of probe fluorescence. The probe exhibits near linear signal response and allows determination of Au and Pd content in aqueous solutions from 0.1 μM.

Paper Details

Date Published: 14 December 2016
PDF: 8 pages
Proc. SPIE 10176, Asia-Pacific Conference on Fundamental Problems of Opto- and Microelectronics, 101760X (14 December 2016);
Show Author Affiliations
A. Mironenko, Institute of Chemistry (Russian Federation)
M. Tutov, Far Eastern Federal Univ. (Russian Federation)
A. Sergeev, Institute for Automation and Control Processes (Russian Federation)
S. Bratskaya, Institute of Chemistry (Russian Federation)

Published in SPIE Proceedings Vol. 10176:
Asia-Pacific Conference on Fundamental Problems of Opto- and Microelectronics
Yuri N. Kulchin; Roman V. Romashko; Alexander V. Syuy, Editor(s)

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