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Proceedings Paper

Short-range structure of fluorine-modified phosphate glass
Author(s): Zoe A. Osborne; Richard K. Brow; David R. Tallant
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Paper Abstract

Raman and x-ray photoelectron spectroscopy are used to characterize the effects of fluorine incorporation on the short range structures of several simple phosphate glasses. Fluorine depolymerizes the chain structure of NaPO3 by replacing bridging POP bonds with terminal PF species. In aluminophosphate glasses with small fluorine contents fluorine is primarily associated with aluminum. When the fluorine to aluminum ratio exceeds three the number of Al-F bonds are maximized and significant numbers of P-F bonds form. 2.

Paper Details

Date Published: 1 October 1990
PDF: 9 pages
Proc. SPIE 1327, Properties and Characteristics of Optical Glass II, (1 October 1990); doi: 10.1117/12.22532
Show Author Affiliations
Zoe A. Osborne, Sandia National Labs. (United States)
Richard K. Brow, Sandia National Labs. (United States)
David R. Tallant, Sandia National Labs. (United States)

Published in SPIE Proceedings Vol. 1327:
Properties and Characteristics of Optical Glass II
Alexander J. Marker III, Editor(s)

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