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Proceedings Paper

Characterization of quantum-confined CuCl microcrystals in a glassy matrix
Author(s): Jacqueline A. Ruller; David A. Dutt; Glen M. Williams; E. Joseph Friebele; Brian L. Justus; Anthony J. Campillo
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Paper Abstract

Quantum confinement effects of semiconductor microcrystallites (CuC1) embedded in a glassy (aluminoborosilicate) matrix are of current interest due to their exceptional nonlinear optical properties. The precipitation of microcrystals occurs upon heat-treatment of a glass in a supersaturated solution. The time and/or temperature of heat-treatment and the degree of supersaturation of the solution determines the size of the microcrystals. This paper characterizes the microcrystals using TEM when the heat-treatment conditions are varied. Room temperature ESR measurements were performed in order to determine the ratio of Cu2 to Cu'' in the glass at various compositions before heat-treatment. Low temperature optical absorption data were jobtained to study the quantum confinement and the effect of varying the microcrystal size. I.

Paper Details

Date Published: 1 October 1990
PDF: 6 pages
Proc. SPIE 1327, Properties and Characteristics of Optical Glass II, (1 October 1990); doi: 10.1117/12.22525
Show Author Affiliations
Jacqueline A. Ruller, Naval Research Lab. (United States)
David A. Dutt, Naval Research Lab. (United States)
Glen M. Williams, Naval Research Lab. (United States)
E. Joseph Friebele, Naval Research Lab. (United States)
Brian L. Justus, Naval Research Lab. (United States)
Anthony J. Campillo, Naval Research Lab. (United States)

Published in SPIE Proceedings Vol. 1327:
Properties and Characteristics of Optical Glass II
Alexander J. Marker III, Editor(s)

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