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Proceedings Paper

Optical and electrochemical properties of sol-gel spin-coated CeO2-TiO2 films
Author(s): Nilgun Ozer; Selmar De Souza; Carl M. Lampert
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Paper Abstract

The optical and electrochemical properties of sol-gel spin coated CeO2-TiO2 (50% CeO2) films were investigated for electrochromic applications. The coating solutions were prepared by using mixed organic-inorganic [Ti(OC2H5)4 and Ce(NH4)2 (NO3)6] precursors. X-ray diffraction studies showed the sol-gel spin- coated films were composed of an amorphous matrix of titanium oxide containing nanocrystallites of cerium oxide. The coating solar transmission value was Ts equals 0.8 (250 nm thick). The refractive index and the extinction coefficient were derived from transmittance measurements in the UV-VIS-NIR regions. These films had refractive index value of n equals 2.18 and extinction coefficient value of k equals 8 X 10-4 at (lambda) equals 550 nm. Cyclic voltametric measurements showed reversible electrochemical insertion of lithium ions in a CeO2-TiO2/LiClO4-propylene carbonate electrochemical cell. During cycling the films maintain high optical transmittance. Spectrophotometric and electrochemical investigations performed on CeO2-TiO2 films revealed that these films are suitable as an optically passive counter-electrode in lithium electrochromic devices.

Paper Details

Date Published: 23 August 1995
PDF: 9 pages
Proc. SPIE 2531, Optical Materials Technology for Energy Efficiency and Solar Energy Conversion XIV, (23 August 1995); doi: 10.1117/12.217327
Show Author Affiliations
Nilgun Ozer, Lawrence Berkeley Lab. (United States)
Selmar De Souza, Lawrence Berkeley Lab. (United States)
Carl M. Lampert, Lawrence Berkeley Lab. (United States)

Published in SPIE Proceedings Vol. 2531:
Optical Materials Technology for Energy Efficiency and Solar Energy Conversion XIV
Carl M. Lampert; Satyen K. Deb; Claes-Goeran Granqvist, Editor(s)

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