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Proceedings Paper

Synthesis of core-shell Y2O3 nanoparticles for enhanced luminescence efficiency
Author(s): Ju H. Choi; Jae Y. Hyun; Ki H. Kim; Jae P. Kim
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Paper Abstract

In this works, rare earth ion doped core and core-shell Y2O3 phosphors have been extensively studied for many applications due to the high stability and emission range and intensity. The core-shell Y2O3: (RE= Eu, Dy, Tb) nanoparticles are synthesized using a two-step process in which 100-150 nm Y2O3 core particles are synthesized using a molten salt synthesis and the shell is deposited using a sol-gel process The core-shell architecture was designed for enhanced luminescence efficiency with long emission lifetimes. Specifically, a multi-shell architecture was necessary to spatially separate Dy3+, Eu3+ and Tb3+ within the phosphor to circumvent the energy transfer to the surface quenching sites. First, the crystallinity of Y2O3nanophosphors was characterized using X-ray analysis. RE-doped Y2O3 core nanoparticles have a good compositional homogeneity. We have also recorded emission spectra and measured fluorescence lifetime. After coating passive shell layer, emission spectra and measured emission lifetimes were compared with those form Y2O3 nanophosphor core system and the effectiveness of these core-shell phosphors were successfully assessed.

Paper Details

Date Published: 11 September 2013
PDF: 7 pages
Proc. SPIE 8808, Active Photonic Materials V, 88081N (11 September 2013); doi: 10.1117/12.2023781
Show Author Affiliations
Ju H. Choi, Korea Photonics Technology Institute (Korea, Republic of)
Jae Y. Hyun, Korea Photonics Technology Institute (Korea, Republic of)
Ki H. Kim, Korea Photonics Technology Institute (Korea, Republic of)
Jae P. Kim, Korea Photonics Technology Institute (Korea, Republic of)

Published in SPIE Proceedings Vol. 8808:
Active Photonic Materials V
Ganapathi S. Subramania; Stavroula Foteinopoulou, Editor(s)

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