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Proceedings Paper

Production of Bi(2D) and BiF(A0+) in a supersonic flow
Author(s): John M. Herbelin; Munson A. Kwok
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Paper Abstract

A series of experiments was conducted in which trimethylbismuthine (TMB) was used to introduce atomic bismuth into a supersonic flow of electronically excited nitrogen fluoride, NF(a1Δ), at an elevated density of 3 x 1015 mol cm-3. Excited-state densities of Bi(2D) approximately equal to 1 x 1013 atom cm-3 and BiF(AO+) approximately equal to 4 x 1O11 mol cm-3 were achieved. After correction for mixing, these density values agreed reasonably well with values predicted by a quadratic scaling law. Simulation of the blue BiF(AO+)-BiF(XO+) emission spectrum suggests that the BiF(AO+) was in vibrational as well as rotational equilibrium at 300°C. The significance of these results for developing a supersonic BiF(AO+) laser utilizing TMB is discussed.

Paper Details

Date Published: 1 June 1990
PDF: 11 pages
Proc. SPIE 1225, High-Power Gas Lasers, (1 June 1990); doi: 10.1117/12.18525
Show Author Affiliations
John M. Herbelin, The Aerospace Corp. (United States)
Munson A. Kwok, The Aerospace Corp. (United States)

Published in SPIE Proceedings Vol. 1225:
High-Power Gas Lasers
Petras V. Avizonis; Charles Freed; Jin J. Kim; Frank K. Tittel, Editor(s)

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