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Proceedings Paper

Enhancement of NCl(b) by excited iodine I(52P1/2)
Author(s): Tientsai T. Yang
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Paper Abstract

A promising candidate for a visible-wavelength chemical laser is the NCl molecule in the b1(Sigma) electronic state, emitting at 665 nm. This state can be generated by purely chemical methods. The energy-pooling reaction, NCl(a1(Delta) ) + I*(P1/2) yields (b1(Sigma) ), is estimated to have a rate coefficient of 1 X 1011 cm3/sec from a steady-state approximation. Experiments using a high speed flowtube have shown that NCl(a1(Delta) ) is generated in high yield via the reaction of HN3 with chlorine atoms. The measured yield is 65%. Preliminary measurements of gain were initiated employing the cavity ring-down technique. These experiments indicate that gain may be present under the operating conditions used. Confirmatory experiments are in progress.

Paper Details

Date Published: 1 June 1994
PDF: 110 pages
Proc. SPIE 2119, Intense Beams and Applications: Lasers, Ions, and Microwaves, (1 June 1994); doi: 10.1117/12.172703
Show Author Affiliations
Tientsai T. Yang, Rockwell International Corp./Rocketdyne Div. (United States)

Published in SPIE Proceedings Vol. 2119:
Intense Beams and Applications: Lasers, Ions, and Microwaves
William E. McDermott, Editor(s)

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