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Proceedings Paper

Fourier transform infrared and Raman study of metal carbonyl clusters: distinction of covalent and dative metal-metal bonds
Author(s): Steven M. Barnett; Stephane H.R. Brienne; Ian S. Butler; Frederick W.B. Einstein; Mike C. Jennings; Jonathan L. Male; Roland K. Pomeroy
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Paper Abstract

Fourier transform infrared and Raman spectroscopy have been used to investigate a number of metal carbonyl clusters involving bonds between osmium and other transition metals. The distinction of covalent and dative metal-metal bonds is discussed with an emphasis on the polarization techniques used in this analysis. The application of permutation theory in the spectroscopic analysis of LM(CO)5 complexes and its use in this analysis are presented.

Paper Details

Date Published: 31 January 1994
PDF: 2 pages
Proc. SPIE 2089, 9th International Conference on Fourier Transform Spectroscopy, (31 January 1994); doi: 10.1117/12.166719
Show Author Affiliations
Steven M. Barnett, McGill Univ. (Canada)
Stephane H.R. Brienne, McGill Univ. (Canada)
Ian S. Butler, McGill Univ. (Canada)
Frederick W.B. Einstein, Simon Fraser Univ. (Canada)
Mike C. Jennings, Simon Fraser Univ. (Canada)
Jonathan L. Male, Simon Fraser Univ. (Canada)
Roland K. Pomeroy, Simon Fraser Univ. (Canada)


Published in SPIE Proceedings Vol. 2089:
9th International Conference on Fourier Transform Spectroscopy
John E. Bertie; Hal Wieser, Editor(s)

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