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Proceedings Paper

Hydrogen bonding in crystalline sugars: a variable-temperature FTIR study on methyl beta-D-galactopyranoside
Author(s): Bert Lutz; Marjan Olthof; Hendrik J. Luinge; John H. van der Maas
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Paper Abstract

Low temperature measurements have been successfully applied to study the H-bond network in methyl-(beta) -D-galactopyranoside in the crystalline phase. Deuterium exchange experiments were required to get insight into vibrational coupling of the OH groups in the chain. Wavenumber-temperature coefficients may be used to characterize the O- H(DOT)(DOT)(DOT)O bonds. The effect of deuterium exchange on H-bond cooperativity is recognized in the OH stretching absorption at approximately 3360 cm-1 and the corresponding OD.

Paper Details

Date Published: 31 January 1994
PDF: 2 pages
Proc. SPIE 2089, 9th International Conference on Fourier Transform Spectroscopy, (31 January 1994); doi: 10.1117/12.166635
Show Author Affiliations
Bert Lutz, Univ. Utrecht (Netherlands)
Marjan Olthof, Univ. Utrecht (Netherlands)
Hendrik J. Luinge, Univ. Utrecht (Netherlands)
John H. van der Maas, Univ. Utrecht (Netherlands)


Published in SPIE Proceedings Vol. 2089:
9th International Conference on Fourier Transform Spectroscopy
John E. Bertie; Hal Wieser, Editor(s)

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