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Proceedings Paper

Fourier transform infrared study of the Van der Waals molecules between alkyl chlorides and hydrogen chloride in liquified argon
Author(s): Benjamin J. van der Veken; Wouter Herrebout
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Paper Abstract

Mid-IR spectra (4000 - 400 cm-1) of mixtures of HCl with methyl-d3, ethyl- d5, n-propyl, isopropyl-d7 or t-butyl chloride, dissolved in liquified argon (95 - 117 K) and liquified krypton (122 - 148 K) have been investigated. In all cases the formation of a 1:1 Van der Waals molecule between HCl and the alkyl chloride was observed. At higher concentrations, a new absorption band, due to a 1:2 complex (RCl)(DOT)(HCl)2 was found. Ab initio structural calculations at the RHF/6-31G** level show the complexes have an approximate L-shape.

Paper Details

Date Published: 31 January 1994
PDF: 2 pages
Proc. SPIE 2089, 9th International Conference on Fourier Transform Spectroscopy, (31 January 1994); doi: 10.1117/12.166581
Show Author Affiliations
Benjamin J. van der Veken, Univ. Ctr. Antwerpen (Belgium)
Wouter Herrebout, Univ. Ctr. Antwerpen (Belgium)

Published in SPIE Proceedings Vol. 2089:
9th International Conference on Fourier Transform Spectroscopy
John E. Bertie; Hal Wieser, Editor(s)

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