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Proceedings Paper

Radial functions for potential energy and related properties of diatomic molecules
Author(s): J. F. Ogilvie
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Paper Abstract

To illustrate the application of the theory described in the accompanying paper, we present results to define radial functions for the potential energy, adiabatic and nonadiabatic vibrational and rotational effects of the diatomic molecules LiH and SiS, including thus both a hydride (for which the effects of partial failure of the Born-Oppenheimer approximation are more readily detectable) and a non-hydride. The problem of current insufficiency of experimental data to permit the general separation of all effects is discussed. Alternative treatments to reduce spectral data are discussed critically in order to assess the dependence of the derived molecular parameters on the nature of the model.

Paper Details

Date Published: 26 January 1994
PDF: 5 pages
Proc. SPIE 2205, 11th Symposium and School on High-Resolution Molecular Spectroscopy, (26 January 1994); doi: 10.1117/12.166191
Show Author Affiliations
J. F. Ogilvie, Institute of Atomic and Molecular Sciences (Taiwan)

Published in SPIE Proceedings Vol. 2205:
11th Symposium and School on High-Resolution Molecular Spectroscopy
Alexander I. Nadezhdinskii; Yu V. Ponomarev; Leonid N. Sinitsa, Editor(s)

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