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Proceedings Paper

Dark reactions between F2 and perfluoroalkyl iodides
Author(s): Ernest A. Dorko; Daniel E. Johnson; E. A. Walters; J. C. Whitehead
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Paper Abstract

The dark reactions between the perfluoroalkyl iodides, CF3I, C2F5I, and C3F7I and F2 have been investigated over a wide range of pressures, flow velocities and temperatures. In addition, the effects of surface and the presence of oxygen have been investigated. The reactions are characterized by an induction time followed by an exponential decrease of the iodide over time. The temperature dependences have been measured and Arrhenius parameters have been calculated. Conclusions concerning the mechanism of the reactions are presented and discussed.

Paper Details

Date Published: 6 June 1993
PDF: 5 pages
Proc. SPIE 1871, Intense Laser Beams and Applications, (6 June 1993); doi: 10.1117/12.145222
Show Author Affiliations
Ernest A. Dorko, Air Force Phillips Lab. (United States)
Daniel E. Johnson, Univ. of New Mexico (United States)
E. A. Walters, Univ. of New Mexico (United States)
J. C. Whitehead, Univ. of Manchester (United Kingdom)

Published in SPIE Proceedings Vol. 1871:
Intense Laser Beams and Applications
William E. McDermott, Editor(s)

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