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Powering up nanoparticles: versatile carbon materials for engineering and medicine
Nanocomposites synthesized from different combinations of nanoparticles and matrix materials demonstrate notably increased strength, thermal stability, and electrical conductivity.
31 October 2008, SPIE Newsroom. DOI: 10.1117/2.1200809.1305
Given carbon's unique properties and versatility,1–4 carbon nanomaterials are being used in an increasing number of engineering and medical applications. For example, when carbon nanoparticles are dispersed in matrix materials like epoxy, polyurethane, rubber, cement, or ice, they confer unique electrical and magnetic properties, unlocking a number of new and exciting applications. When such materials are placed under strain, changes in electrical resistance (piezoresistive) and magnetic properties (piezomagnetic) emerge. In an electrolyte, the materials can expand due to an applied voltage.3
An interdisciplinary research team5 is developing carbon materials for commercialization in products such as spray-on continuous sensors for structural health monitoring (SHM), smart nanocomposites that are self-sensing, nanoreinforced laminated composites (NRLCs) that are tough in shear, and carbon nanotube (CNT) electrical fibers. This article provides a summary of how these composites are being developed at our facility to form different prototypes for diverse applications.
Figure 1. Nanomaterials for engineering and medical applications: (a) carbon nanofibers (CNFs) produced by Applied Sciences Inc., (b) carbon nanosphere chains (CNSCs) produced by Clean Technologies Inc., and (c) an 11mm-long carbon nanotube (CNT) array produced by the University of Cincinnati.
Carbon nanofibers (CNFs) are multiwall, highly graphitic, low-cost fibers6 with diameters ranging from 70 to 200 nm and lengths up to a few hundred microns: see Figure 1(a). The fiber walls sit at an angle of about 20 degrees to the fiber axis and terminate along the surface of the fiber in a zigzag form. Remarkably, a relatively small loading of CNFs in a polymer matrix material can improve its mechanical properties and affect its electrical conductivity, piezoresistive, electromagnetic shielding, and heat dissipation characteristics. As such, promising CNF water-based nanofluids are currently being evaluated for heat-exchange applications. The cost of high-grade PR-25 CNF material is low, at about $125/lb. Furthermore, the material is well characterized and produced in tons per year,6 making it ideal for use in an array of applications.
Carbon nanosphere chains (CNSCs) are a novel nanostructured material with a spherical morphology—see Figure 1(b)—and a high electrical conductivity that can be postprocessed to have magnetic properties.7 CNSCs are unique because they are the only documented carbon nanoparticle that has high electrical conductivity and weak magnetic properties. Postprocessing can tailor these properties for applications in smart polymeric nanocomposites and magnetic materials. Different materials built using CNSCs are shown in Figure 2, including a magnetic pellet formed using high-pressure fabrication methods and structural nanoskins that are electrically conductive on one side and insulating on the other. CNSCs can be produced in large volume, and their cost is expected to be moderate.
Figure 2. Smart CNSC nanocomposites: (a) magnetic pellet, (b) CNSC-polyvinyl alcohol structural nanoskin, and (c) CNSC-epoxy nanoskin.
Figure 3. CNT spray-on continuous sensors.
CNTs produced by chemical vapor deposition can be synthesized in arrays to form structures that are nanometers in diameter and that range from a few microns long to 1.8cm: see Figure 1(c). CNTs grown in an array or forest are called Black Cotton™.8, 9 This material holds promise for developing unique and revolutionary strain sensors, actuators, biosensors, and nanocomposites for multifunctional applications. When fabricated as a long film, CNTs can function as long continuous sensors (see Figure 3). A structural neural system (SNS) can be fabricated using a dispersed nanoparticle solution applied with an airbrush on a patterned surface to form a grid pattern. The electrochemical impedance (resistance and capacitance) of the SNS changes due to deterioration of the structure where the neuron is located. As such, SNSs can be used to detect cracking of bridge supports early enough to prevent collapse of the structure. CNT arrays presently have a high cost, thereby limiting their application, but the cost will decline as production increases.
Other unique applications also take advantage of the structure and properties of CNT arrays. For example, interlaminar materials are subject to stress cracks propagated along the interlaminar planes. To address this problem, a prototype NRLC is being developed (see Figure 4). The NRLC is composed of layered microfiber textile cloth in a polymeric matrix with nanoscale reinforcements in the form of multiwalled CNT cores that pass transversely between each set of plies. Besides shear reinforcement, the CNT cores also alter the electrical conductivity through the thickness of the laminated composites. Therefore, electrodes can be sputtered on the surface of the laminate, and the electrical impedance through the thickness of the laminate can be monitored to detect cracking or delamination. The NRLC is thus a responsive multifunctional material with improved shear strength and stiffness that also self-senses damage.
Figure 4. Nanoreinforced laminated composite (NRLC) design: CNT array attached to tape and placed onto a nanoreinforced carbon woven fabric composite ply and the CNT array bonded to the carbon fabric.
The versatility of nanoscale materials is rapidly expanding, and engineers are only now realizing their full potential. Other multifunctional materials in development are CNT threads and sheets10–12 (see Figure 5). These CNT forms may be used to make smart fabrics with several unique properties, including reinforced fabric composites (for use in garments for soldiers, firefighters, and first responders), electromagnetic radiation shielding, or SHM sensors. Furthermore, because of their inherent strength and inert nature, there are several medical applications for CNTs currently under development, including small nanotube electrodes that can penetrate an individual living cell, which might be used as tiny biosensors, and nanotube scaffolds that can be used to culture neurons in hopes of repairing damage to the central nervous system. As we further explore the unique properties of different nanocomposites, their potential may further inspire other unique applications.
Figure 5. (a) Optical image of CNT thread spun directly from the array and scanning electron microscope image of fine-spun CNT thread with an average diameter of 3.5μm. (b) Carbon nanotube ribbon greater than 1m long being pulled from a CNT array.
Gunjan Maheshwari, Nilanjan Mallik, Jandro Abot, Albert Song, Emily Head, Vesselin Shanov, Mark Schulz, Chaminda Jayasinghe, Pravahan Salunke, YeoHeung Yun
Department of Mechanical Engineering
University of Cincinnati
Gunjan Maheshwari is an MS student. His research is focused on developing, characterizing, and modeling smart nanocomposites for use in industrial health monitoring.
North Carolina A&T State University
2. A. Bogdanovich, P. Bradford, D. Mungalov, S. Fang, M. Zhang, R. H. Baughman, S. Hudson, Fabrication and mechanical characterization of carbon nanotube yarns, 3-D braids, and their composites, SAMPE J. 43, no. 1, pp. 6-19, 2006.
4. G. Maheshwari, N. Mallik, J. Abot, A. Song, E. Head, M. Dadhania, V. Shanov, C. Jayasinghe, P. Salunke, L. Lee, D. Hurd, Y. Yun, S. Yarmolenko, J. Sankar, P. Phillips, R. A. Komoroski, W.-J. Chu, A. Bhattacharya, N. Watts, M. J. Schulz, Nanoscale materials for engineering and medicine, Proc. SPIE 6931, 2008. doi:10.1117/12.782591
. Applied Sciences Inc. and Pyrograf Products Inc., Cedarville, OH. Accessed 15 September 2008.
11. Y.-H. Li, J. Wei, X. Zhang, C. Xu, D. Wu, L. Lu, B. Wei, Mechanical and electrical properties of carbon nanotube ribbons, Chem. Phys. Lett. 365, no. 1–2, pp. 95-100, 2002.
12. A. Lobovsky, J. Matrunich, M. Kozlov, R. C. Morris, R. H. Baughman, A. A. Zakhidov, Spinning, processing, and applications of carbon nanotube filaments, ribbons, and yarns, US Patent 6682677, 2004.