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Proceedings Paper

Time-resolved Infrared Studies Of Coordinatively Unsaturated Metal Carbonyl Species
Author(s): Avtar S. Nazran; Michel Drouin; David M. Rayner; Peter A. Hackett
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Paper Abstract

Fast laser based time-resolved infrared absorption spectroscopy has been applied to the study of the ultraviolet photolysis of the pseudo-nickel carbonyl, tricarbonylnitrosocobalt. The kinetics of the disappearance of the starting molecule and the formation of a coordinatively unsaturated cobalt species, tentatively assigned as Co(C0)2, have been observed. Rate constants for the secondary reaction of this species with the parent compound, and with CO, have been determined. A reaction mechanism is proposed.

Paper Details

Date Published: 20 December 1985
PDF: 2 pages
Proc. SPIE 0553, Fourier and Computerized Infrared Spectroscopy, (20 December 1985); doi: 10.1117/12.970890
Show Author Affiliations
Avtar S. Nazran, National Research Council (Canada)
Michel Drouin, National Research Council (Canada)
David M. Rayner, National Research Council (Canada)
Peter A. Hackett, National Research Council (Canada)


Published in SPIE Proceedings Vol. 0553:
Fourier and Computerized Infrared Spectroscopy
David G. Cameron; Jeannette G. Grasselli, Editor(s)

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