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Proceedings Paper

Resonance Raman Studies Of Copper(II) Octaethylisobacteriochlorin
Author(s): David F. Bocian; Alexander D. Procyk; Jeffrey M. Peloquin
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Paper Abstract

Resonance Raman spectra are reported for the copper(II) complex of trans-octaethylisobacteriochlorin with excitation in the B and Qy absorption bands. Assignments are proposed for a number of the high-frequency (above 1400 cm-1) skeletal modes of the macrocycle. Normal coordinate calculations are also performed on the complex. These calculations indicate that the normal coordinates of isobacteriochlorins bear little resemblance to those of porphyrins or chlorins.

Paper Details

Date Published: 8 May 1989
PDF: 8 pages
Proc. SPIE 1057, Biomolecular Spectroscopy, (8 May 1989); doi: 10.1117/12.951657
Show Author Affiliations
David F. Bocian, Carnegie Mellon University (United States)
Alexander D. Procyk, Carnegie Mellon University (United States)
Jeffrey M. Peloquin, Carnegie Mellon University (United States)

Published in SPIE Proceedings Vol. 1057:
Biomolecular Spectroscopy
Robert R. Birge; Henry H. Mantsch, Editor(s)

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