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Proceedings Paper

Photoionization Of Small Molecules Using Synchrotron Radiation
Author(s): T A Ferrett; A C Parr
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Paper Abstract

We report here new high-resolution vibrationally resolved studies of photoionization in the molecules CO and CO2 using synchrotron radiation in the photon-energy range 10-30 eV. The detailed decay dynamics of autoionizing resonances in CO and the origin of symmetry-forbidden vibrational transitions in the C state of CO2+ are discussed. These examples illustrate the need for experimental work with both high optical resolution and electron resolution sufficient to resolve the complex resonances in molecules and the vibrational dependence of molecular dynamics.

Paper Details

Date Published: 11 July 1988
PDF: 4 pages
Proc. SPIE 0911, X-Ray and Vacuum Ultraviolet Interaction Data Bases, Calculations, and Measurements, (11 July 1988); doi: 10.1117/12.945470
Show Author Affiliations
T A Ferrett, National Bureau of Standards (United States)
A C Parr, National Bureau of Standards (United States)


Published in SPIE Proceedings Vol. 0911:
X-Ray and Vacuum Ultraviolet Interaction Data Bases, Calculations, and Measurements
Nancy DelGrande; James A. R. Samson; David Y. Smith, Editor(s)

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