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Proceedings Paper

Photochemistry Of Adsorbed Organometallics: Fe(CO)5 on SiO2
Author(s): Robert L. Jackson
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Paper Abstract

The photochemistry of Fe(CO)5 adsorbed on Si02 at submonolayer coverage has been studied. IR and UV-visible spectra show that the only significant product is Fe3(C0)12 rather than Fe2(C0)9, which is the product observed upon irradiation of Fe(C0)5 in the gas or liquid phase or in solution. Evidence is presented that the intermediate reacting to give Fe3(CO)12 on the Si02 surface is a species designated Fe(C0)4(Si02), which denotes a complex between Fe(C0)4 and the terminal surface hydroxyl groups or siloxane bridging oxo groups.

Paper Details

Date Published: 14 June 1984
PDF: 9 pages
Proc. SPIE 0459, Laser-Assisted Deposition, Etching, and Doping, (14 June 1984); doi: 10.1117/12.939432
Show Author Affiliations
Robert L. Jackson, Allied Corporation (United States)

Published in SPIE Proceedings Vol. 0459:
Laser-Assisted Deposition, Etching, and Doping
Susan Davis Allen, Editor(s)

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