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Proceedings Paper

Infrared Multiphoton Dissociation Of Hexafluoroethane
Author(s): C E Brown; J Reid; D R Smith
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Paper Abstract

The infrared multiphoton dissociation (IRMPD) of "neat" hexafluoroethane has been investigated for the first time. The stable products of photolysis are measured by IR absorption spectroscopy with a tunable lead-salt diode laser (TDL), which offers high sensitivity combined with a non-destructive measuring technique. The high sensitivity and resolution of the TDL allow measurement of the major stable products CF4 and C2F4 after irradiation by a single infrared laser pulse. A mechanism of IRMPD of C2F6 is proposed.

Paper Details

Date Published: 25 November 1986
PDF: 4 pages
Proc. SPIE 0669, Laser Applications in Chemistry, (25 November 1986); doi: 10.1117/12.938934
Show Author Affiliations
C E Brown, McMaster University (Canada)
J Reid, McMaster University (Canada)
D R Smith, McMaster University (Canada)


Published in SPIE Proceedings Vol. 0669:
Laser Applications in Chemistry
D. K. Evans, Editor(s)

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