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Proceedings Paper

Preparation and photoelectric properties of poly(phenylethanone)- manganese phthalocyanine derivative for polymer photovoltaic cells
Author(s): Benhua Pei; Yue Shen; Wangxi Cheng; Feng Gu; Jiancheng Zhang
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Paper Abstract

A novel soluble poly(phenylethanone) derivative grafted with tetra-acyl-chlorich manganese phthalocyanine (TACMnPc) was synthesized via esterification and characterized by electronic absorption spectrum and fluorescence spectra. The derivative (PPE-MnPc) exhibits high solubility and excellent film-forming property. Electronic absorption spectrum of the polymer exhibits a Q-band peak positioned at about 736 nm, which is obviously red shifted compared with 2, 9, 16, 23-tetra-carboxyl manganese(II) phthalocyanine (TCMnPc). PPE-MnPc films were prepared by dip-coating technology. Photoconductivity of PPE-MnPc films was characterized by current-voltage measurement. At bias voltage of 20 V, photoconductivity of the film was 6.8×10-9 S and dark conductivity was 7.5 ×10-10 S. The electrical conductivity of PPE-MnPc films under irradiation was nine times higher than that in the dark, which indicated that PPE-MnPc had a good photovoltaic response.

Paper Details

Date Published: 18 February 2011
PDF: 4 pages
Proc. SPIE 7995, Seventh International Conference on Thin Film Physics and Applications, 799505 (18 February 2011); doi: 10.1117/12.888205
Show Author Affiliations
Benhua Pei, Shanghai Univ. (China)
Yue Shen, Shanghai Univ. (China)
Wangxi Cheng, Shanghai Univ. (China)
Feng Gu, Shanghai Univ. (China)
Jiancheng Zhang, Shanghai Univ. (China)


Published in SPIE Proceedings Vol. 7995:
Seventh International Conference on Thin Film Physics and Applications
Junhao Chu; Zhanshan Wang, Editor(s)

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