Share Email Print
cover

Proceedings Paper

GaN-nanowire/ TiO2-nanocluster hybrid sensors for detection of Benzene and related aromatic compounds
Author(s): Geetha S. Aluri; Abhishek Motayed; Albert V. Davydov; Vladimir Oleshko; Kris A. Bertness; Norman A. Sanford; Mulpuri V. Rao
Format Member Price Non-Member Price
PDF $17.00 $21.00
cover GOOD NEWS! Your organization subscribes to the SPIE Digital Library. You may be able to download this paper for free. Check Access

Paper Abstract

Nanowire-nanocluster hybrid chemical sensors were realized by functionalizing gallium nitride (GaN) nanowires with titanium dioxide (TiO2) nanoclusters for selectively sensing Benzene and other related aromatic compounds. Hybrid sensor devices were developed by fabricating two-terminal devices using individual GaN nanowires followed by the deposition of TiO2 nanoclusters using RF magnetron sputtering. The sensor fabrication process employed all standard micro-fabrication techniques. A change of current was observed for these hybrid sensors when exposed to aromatic compounds such as Benzene, Toluene, Ethylbenzene, Xylene, and Chlorobenzene mixed with air. However, these sensors did not show any sensitivity when exposed to Methanol, Ethanol, Isopropanol, Chloroform, Acetone, and 1, 3-Hexadiene. These sensors were capable of sensing the aromatic compounds only under ultraviolet excitation. The sensitivity range for the above mentioned aromatic compounds varied from 1% down to 50 parts per billion (ppb) at room-temperature. By combining the enhanced catalytic properties of the TiO2 nanoclusters with the sensitive transduction capability of the nanowires, an ultra-sensitive and highly selective chemical sensing architecture is demonstrated. We have proposed a mechanism that could qualitatively explain the observed sensing behavior.

Paper Details

Date Published: 26 May 2011
PDF: 10 pages
Proc. SPIE 8024, Advanced Environmental, Chemical, and Biological Sensing Technologies VIII, 80240M (26 May 2011); doi: 10.1117/12.883970
Show Author Affiliations
Geetha S. Aluri, National Institute of Standards and Technology (United States)
George Mason Univ. (United States)
Abhishek Motayed, National Institute of Standards and Technology (United States)
Univ. of Maryland, College Park (United States)
Albert V. Davydov, National Institute of Standards and Technology (United States)
Vladimir Oleshko, National Institute of Standards and Technology (United States)
Kris A. Bertness, National Institute of Standards and Technology (United States)
Norman A. Sanford, National Institute of Standards and Technology (United States)
Mulpuri V. Rao, George Mason Univ. (United States)


Published in SPIE Proceedings Vol. 8024:
Advanced Environmental, Chemical, and Biological Sensing Technologies VIII
Tuan Vo-Dinh; Robert A. Lieberman; Günter Gauglitz, Editor(s)

© SPIE. Terms of Use
Back to Top