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Proceedings Paper

Relaxor fluorinated polymers: novel applications and recent developments
Author(s): François Bauer; Domingues Dos Santos; Qiming Zhang
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Paper Abstract

It has been found that by introducing defects into the P(VDF-TrFE) copolymers, it is possible to convert the polymer from a normal ferroelectric to a relaxor ferroelectric. A new class of ferroelectric polymers, i.e., the terpolymers of P(VDF-TrFE-CFE) or of P(VDF-TrFE-CTFE), was developed from the normal ferroelectric PVDF-TrFE polymer by employing proper defect modifications which eliminate detrimental effects associated with a normal first order F-P transition while maintaining high material responses. Relevant studies show that this class of electroactive polymers offers unique properties in comparison with other ferroelectric polymers. The syntheses of these relaxor ferroelectric polymers have been done by a combination of the suspension polymerization process and an oxygen-activated initiator at a temperature of 40 °C. Films from cast solution can be made in different length and thicknesses. Stretching of these films increases the performance as well as the mechanical properties. These relaxor-ferroelectric terpolymers P(VDF-TrFE-CFE), P(VDF-TrFE-CTFE) are multifunctional i.e. electrostrictive material, dielectric for electric energy storage. The terpolymer exhibits high electrostrictive strain (>7%) with relatively high modulus (>0.4GPa). Examples of devices applications using unimorphe systems are presented. Micropump and Optical device concerning a liquid-filled varifocal lens on a chip are described.

Paper Details

Date Published: 28 March 2011
PDF: 9 pages
Proc. SPIE 7976, Electroactive Polymer Actuators and Devices (EAPAD) 2011, 79761Y (28 March 2011); doi: 10.1117/12.879586
Show Author Affiliations
François Bauer, Piezotech S.A.S. (France)
Domingues Dos Santos, Piezotech S.A.S. (France)
Qiming Zhang, The Pennsylvania State Univ. (United States)

Published in SPIE Proceedings Vol. 7976:
Electroactive Polymer Actuators and Devices (EAPAD) 2011
Yoseph Bar-Cohen; Federico Carpi, Editor(s)

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