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Proceedings Paper

Preparation of magnetic fluorescent hollow nanoparticles with multi-layer
Author(s): Xiuxue Sun; Jimei Zhang; Zhao Dai; Ping Li; Wen Zhou; Guo Zheng
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Paper Abstract

A kind of novel magnetic fluorescent hollow nanoparticles with multi-layer shells by layer-by-layer self-assembly process was presented in this paper. Non-crosslinking poly(acrylic acid) (PAA) nanoparticles as core with 250 nm in diameters were prepared by distillation-precipitation polymerization in acetonitrile with 2, 2'-Azobisisobutyronitrile (AIBN) as initiator and without any stabilizer and crosslinker. Then 4-vinylpyridine (4-VPy) as monomer was selfassembled on the surface of PAA nanoparticles because of hydrogen-bonding effect between the surface carboxyl of PAA nanoparticles and pyridine of 4-VPy. The 4-VPy as first shell layer were crosslinked by ethylene glycol dimethacrylate (EGDMA) by seeds distillation-precipitation polymerization in acetonitrile. The core/shell structure of this kind of nanoparticles was investigated by FT-IR and TEM. We can find that the products had an absorption peak at 1641 cm-1 from the FT-IR, which showed that the vinyl groups had been connected in the polyAA microspheres. After that, the non-crosslinking PAA core was removed under a solution of sodium hydroxide in ethanol-water. On the other hand, CdTe quantum dots (QDs) with about 3 nm in diameters as shell were prepared in aqueous solution with 3- mercaptopropionic acid (MPA) as stabilizer and 1, 6-hexylenediamime modified Fe3O4 nanoparticles with about 11 nm in diameters as core were synthesized in water respectively. Because of the hydrogen-bonding between the surface carboxyl of MPA on CdTe QDs and the amino on Fe3O4 nanoparticles, the core/shell magnetic-fluorescent nanoparticles were obtained. Then, the magnetic-fluorescent nanoparticles as second shell layer were self-assembled on the hollow 4VPy nanoparticles.

Paper Details

Date Published: 20 October 2009
PDF: 8 pages
Proc. SPIE 7493, Second International Conference on Smart Materials and Nanotechnology in Engineering, 74935Y (20 October 2009); doi: 10.1117/12.840003
Show Author Affiliations
Xiuxue Sun, Tianjin Polytechnic Univ. (China)
Jimei Zhang, Tianjin Polytechnic Univ. (China)
Zhao Dai, Tianjin Polytechnic Univ. (China)
Ping Li, Tianjin Polytechnic Univ. (China)
Wen Zhou, Tianjin Polytechnic Univ. (China)
Guo Zheng, Tianjin Polytechnic Univ. (China)

Published in SPIE Proceedings Vol. 7493:
Second International Conference on Smart Materials and Nanotechnology in Engineering
Jinsong Leng; Anand K. Asundi; Wolfgang Ecke, Editor(s)

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