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Proceedings Paper

Synthesis and characterization of organic-inorganic polymers from new methacrylate monomers and silane derivatives
Author(s): F. Adriana Nicolescu; Victor V. Jerca; Ana M. Albu; D. Sorin Vasilescu; D. Mircea Vuluga
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Paper Abstract

We report the synthesis of five new hybrid polymeric structures obtained by free radical copolymerization of some organic azo-based methacrylate monomers and 3-methacryloxypropyl trimethoxysilane (MEMO). The copolymers are soluble in common solvents like methylene chloride, chloroform, dichlorbenzene, dimethylsulfoxide, dimethylformamide. The copolymeric structures might be interesting from the point of view of nonlinear optical response due to a rich content in chromophoric units determined by H-NMR spectroscopy. The structures were also characterized by FT-IR spectroscopy, TGA and SEC analysis.

Paper Details

Date Published: 24 September 2009
PDF: 7 pages
Proc. SPIE 7487, Optical Materials in Defence Systems Technology VI, 74870N (24 September 2009); doi: 10.1117/12.832282
Show Author Affiliations
F. Adriana Nicolescu, Ctr. for Organic Chemistry Costin D. Nenitescu (Romania)
Victor V. Jerca, Ctr. for Organic Chemistry Costin D. Nenitescu (Romania)
Ana M. Albu, Ctr. for Organic Chemistry Costin D. Nenitescu (Romania)
Univ. Politehnica of Bucharest (Romania)
D. Sorin Vasilescu, Univ. Politehnica of Bucharest (Romania)
D. Mircea Vuluga, Ctr. for Organic Chemistry Costin D. Nenitescu (Romania)


Published in SPIE Proceedings Vol. 7487:
Optical Materials in Defence Systems Technology VI
James G. Grote; François Kajzar; Roberto Zamboni, Editor(s)

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