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Proceedings Paper

Labeling of pure vibrational states of water-like molecules
Author(s): O. V. Naumenko; E. R. Polovtseva
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Paper Abstract

A problem of the consistent normal mode labeling for water-like molecules is discussed based on the effective vibrational Hamiltonian approach. The main contributions to the resulting vibrational wave functions of the H2S molecule are presented. It is shown that due to resonance mixing, the proposed normal mode notations of the highly excited vibrational states of H2S become ambiguous for the energies higher than 12000 cm-1 and have to be used with caution.

Paper Details

Date Published: 11 February 2009
PDF: 6 pages
Proc. SPIE 7296, Fifteenth International Symposium on Atmospheric and Ocean Optics/Atmospheric Physics, 729602 (11 February 2009); doi: 10.1117/12.820961
Show Author Affiliations
O. V. Naumenko, Institute of Atmospheric Optics SB RAS (Russian Federation)
E. R. Polovtseva, Institute of Atmospheric Optics SB RAS (Russian Federation)


Published in SPIE Proceedings Vol. 7296:
Fifteenth International Symposium on Atmospheric and Ocean Optics/Atmospheric Physics

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