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Proceedings Paper

Photo-physical properties and triplet-triplet absorption of platinum(II) acetylides in solid PMMA matrices
Author(s): Eirik Glimsdal; Robert Westlund; Mikael Lindgren
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Paper Abstract

Because of their strong nonlinear optical properties, Platinum(II) acetylides are investigated as potential chromophores for optical power limiting (OPL) applications. The strong excited state absorption and efficient intersystem crossing to the triplet states in these materials are desired properties for good OPL performance. We recently reported on OPL and photo-physical properties of Pt(II)-acetylide chromophores in solution, modified with thiophenyl or triazole groups. [R. Westlund et al. J. Mater. Chem. 18, 166 (2008); E. Glimsdal et al. Proc. SPIE 6740, 67400M (2007)] The chromophores were later incorporated into poly(methyl-methacrylate) (PMMA) glasses. A variety of doped organic solids were prepared, reaching concentrations of up to 13 wt% of the guest molecule. Raman spectra of the doped solid devices proved that the chemical structure of the nonlinear dyes remains intact upon the polymerization of the solid matrix. Luminescence spectra confirm that the basic photo-physical properties (absorption, emission and inter-system crossing) observed for the solute molecules in THF are maintained also in the solid state. In particular, the phosphorescence lifetime stays in the order of μs to ms, just as in the oxygen evacuated liquid samples. Also, the wavelength dependence and time-dynamics of the triplet absorption spectra of the dyes, dissolved in THF solution and dispersed in solid PMMA matrices, were investigated and compared. Ground state UV absorption spectra between 300 and 420 nm have corresponding broad band visible triplet-triplet absorption between 400 and 800 nm. The triplet state extinction coefficients were determined to be in the order of 104 M-1cm-1.

Paper Details

Date Published: 28 May 2009
PDF: 9 pages
Proc. SPIE 7354, Nonlinear Optics and Applications III, 73540H (28 May 2009); doi: 10.1117/12.820645
Show Author Affiliations
Eirik Glimsdal, Norwegian Univ. of Science and Technology (Norway)
Robert Westlund, Royal Institute of Technology (KTH) (Sweden)
Mikael Lindgren, Norwegian Univ. of Science and Technology (Norway)

Published in SPIE Proceedings Vol. 7354:
Nonlinear Optics and Applications III
Mario Bertolotti, Editor(s)

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