Share Email Print
cover

Proceedings Paper

Shape memory miscible blends for thermal mending
Author(s): Erika D. Rodriguez; Xiaofan Luo; Patrick T. Mather
Format Member Price Non-Member Price
PDF $14.40 $18.00
cover GOOD NEWS! Your organization subscribes to the SPIE Digital Library. You may be able to download this paper for free. Check Access

Paper Abstract

We report on miscible blends comprised of linear-poly(ε-caprolactone) (l-PCL) and chemically crosslinked network- PCL (n-PCL). The blends demonstrate unique Shape Memory Assisted Self-Healing (SMASH) property, which is the materials ability to close local microscopic cracks and heal those cracks by bonding the crack surfaces. For Shape Memory (SM) characterization, temporary deformation of the networks was achieved at room temperature. Samples were temporarily fixed below their crystalline temperature (Tc) and shape recovery was triggered by a temperature above the blends melting temperature (Tm). Thermogravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC) were used to study the thermal properties of the blends and Dynamic Mechanical Analysis (DMA) and small-scale tensile testing were used to obtain the mechanical properties and self-healing efficiencies of the blends.

Paper Details

Date Published: 31 March 2009
PDF: 5 pages
Proc. SPIE 7289, Behavior and Mechanics of Multifunctional Materials and Composites 2009, 728912 (31 March 2009); doi: 10.1117/12.816042
Show Author Affiliations
Erika D. Rodriguez, Syracuse Univ. (United States)
Xiaofan Luo, Syracuse Univ. (United States)
Patrick T. Mather, Syracuse Univ. (United States)


Published in SPIE Proceedings Vol. 7289:
Behavior and Mechanics of Multifunctional Materials and Composites 2009
Zoubeida Ounaies; Jiangyu Li, Editor(s)

© SPIE. Terms of Use
Back to Top