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Proceedings Paper

Photoresponsive polymers containing side-chain chiral azocarbazole chromophores as multifunctional materials
Author(s): Renato Bozio; Tiziano Dainese; Loris Giorgini; Attilio Golemme; Francesco Mauriello; Danilo Pedron; Roberto Termine
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Paper Abstract

A new optically active photochromic polymethacrylate containing the carbazole moiety, deriving from the chiral monomer (S)-(4-cyanophenyl)-[3-[9-[2-(2-methacryloyloxypropanoyloxy) ethyl]carbazolyl]]diazene [(S)-MLECA] has been prepared and fully characterized with the aim to obtain a multifunctional material which can be considered at the same time as a photonic material for NLO and optical storage, for chiroptical switches, and for photorefractive and photoconductive applications. The complete reversibility of the photoinduced linear birefringence, which is related to fatigue resistance properties seems to be promising for use in optical storage or more generally in the field of photoresponsive systems, and it is not necessary to add dopants in order to observe photoconduction thanks to the presence of the carbazole moiety, which is well known for its hole conducting properties.

Paper Details

Date Published: 13 September 2007
PDF: 8 pages
Proc. SPIE 6653, Linear and Nonlinear Optics of Organic Materials VII, 665305 (13 September 2007); doi: 10.1117/12.767513
Show Author Affiliations
Renato Bozio, Univ. di Padova (Italy)
Tiziano Dainese, Univ. di Padova (Italy)
Loris Giorgini, Univ. degli Studi di Bologna (Italy)
Attilio Golemme, Univ. della Calabria (Italy)
Francesco Mauriello, Univ. degli Studi di Bologna (Italy)
Danilo Pedron, Univ. di Padova (Italy)
Roberto Termine, Lab. Licryl, CNR-INFM, e Centro di Eccellenza, CEMIF.CAL (Italy)

Published in SPIE Proceedings Vol. 6653:
Linear and Nonlinear Optics of Organic Materials VII
Jean-Michel Nunzi, Editor(s)

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