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Proceedings Paper

Fluorescence in the system Eu(III) - oxytetracycline - co-ligand -sodium dodecylbenzene sulphonate micelles and its analytical application
Author(s): Sergei N. Shtykov; Tatyana D. Smirnova; Natalja V. Kalashnikova; Yurii G. Bylinkin; Dmitry A. Zhemerichkin
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Paper Abstract

Fluorescence enhancement of the Eu3+ - oxytetracycline (OTC) chelate by addition of phenanthroline (Phen) and trioctyiphosphine oxide (TOPO) as well as micelles of anionic, catiomic and nonionic surfactants has been studied. As was found, in the presence of Phen as co-ligand and micelles of dodecylbenzene sulfonate as anionic surfactant the analytical signal increased by a factor of 8.5 and reached maximum value at pH 8.0 ± 0.5. The dynamic concentration range of OTC determination was found to be 8.0 x 10-8 - 4.0 × 10-5 M (R2 = 0.991) and the detection limit 5.3 × 10-8 M (3 σ criterion). The procedure based on europium-sensitized fluorescence has been developed for the determination of OTC in chicken meat with the recovery of 98.0-103.3%.

Paper Details

Date Published: 8 August 2006
PDF: 7 pages
Proc. SPIE 6165, Saratov Fall Meeting 2005: Laser Physics and Photonics, Spectroscopy and Molecular Modeling VI, 61650Q (8 August 2006); doi: 10.1117/12.696852
Show Author Affiliations
Sergei N. Shtykov, Saratov State Univ. (Russia)
Tatyana D. Smirnova, Saratov State Univ. (Russia)
Natalja V. Kalashnikova, Saratov State Univ. (Russia)
Yurii G. Bylinkin, Saratov State Univ. (Russia)
Dmitry A. Zhemerichkin, Nita-Pharm Saratov (Russia)


Published in SPIE Proceedings Vol. 6165:
Saratov Fall Meeting 2005: Laser Physics and Photonics, Spectroscopy and Molecular Modeling VI
Vladimir L. Derbov; Leonid A. Melnikov; Lev M. Babkov, Editor(s)

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