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Proceedings Paper

Control and switching of first hyperpolarizability by pH
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Paper Abstract

Modulating the electronic, magnetic and optical properties at the molecular level using an external trigger has been extended to the field of nonlinear optics. The switching molecule is designed to have a complexation site or a redox active unit which can guarantee electronic communication over the whole conjugated system. The alteration of the nonlinear property is then induced by the modulation of the internal charge-transfer due to the response of the molecule to the external stimulus. This can be achieved by cation binding, protonation/deprotonation or electrochemically.

Paper Details

Date Published: 14 September 2006
PDF: 10 pages
Proc. SPIE 6331, Linear and Nonlinear Optics of Organic Materials VI, 633104 (14 September 2006); doi: 10.1117/12.678027
Show Author Affiliations
Inge Asselberghs, Katholieke Univ. Leuven (Belgium)
Gunther Hennrich, Univ. Autónomade Madrid (Spain)
Benjamin J. Coe, Univ. of Manchester (United Kingdom)
Koen Clays, Katholieke Univ. Leuven (Belgium)


Published in SPIE Proceedings Vol. 6331:
Linear and Nonlinear Optics of Organic Materials VI
Robert A. Norwood, Editor(s)

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