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Synthesis, characterization, and differentiation of high energy amine peroxides by MS and vibrational microscopy
Author(s): Alvaro J. Peña-Quevedo; Nairmen Mina-Calmide; Nelmary Rodríguez; Deborah Nieves; Robert B. Cody; Samuel P. Hernández-Rivera
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Paper Abstract

Synthesis and characterization of hexamethelene triperoxide diamine (HMTD), tetramethylene diperoxide dicarbamide (TMDD) and tetramethylene diperoxide acetamide (TMDA) using GC-MS, HPLC-MS, FT-IR and Raman Microscopy has been carried out. The study also centered in the synthesis and characterization of other cyclic amine peroxides, including and different forms of caged peroxides from other diaminoalkanes. Interest also was given to the secondary products of all syntheses and the effect of temperature in the composition mixtures of the preparations. Differentiation spectroscopy and spectrometry studies were also conducted. In these studies the differences in the ν(O-O), ν(N-C), ν(N-H), ν(C-O), δ(CH3-C) and δ(C-O) bands for Raman and IR were established. For the GC/MS spectrometric studies retention times and fragmentation patterns for GC-MS and GC-FT-IR useful in amine peroxide differentiation were also established.

Paper Details

Date Published: 10 May 2006
PDF: 10 pages
Proc. SPIE 6201, Sensors, and Command, Control, Communications, and Intelligence (C3I) Technologies for Homeland Security and Homeland Defense V, 62012E (10 May 2006); doi: 10.1117/12.666202
Show Author Affiliations
Alvaro J. Peña-Quevedo, Univ. of Puerto Rico Mayagüez (United States)
Nairmen Mina-Calmide, Univ. of Puerto Rico Mayagüez (United States)
Nelmary Rodríguez, Univ. of Puerto Rico Mayagüez (United States)
Deborah Nieves, Univ. of Puerto Rico Mayagüez (United States)
Robert B. Cody, JEOL USA, Inc. (United States)
Samuel P. Hernández-Rivera, Univ. of Puerto Rico Mayagüez (United States)


Published in SPIE Proceedings Vol. 6201:
Sensors, and Command, Control, Communications, and Intelligence (C3I) Technologies for Homeland Security and Homeland Defense V
Edward M. Carapezza, Editor(s)

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